Polymer Science Faculty Research

Title

Watching nucleation and growth of chain disentanglement in large-amplitude oscillatory shear of entangled polymer solutions

Document Type

Article

Publication Date

Spring 2006

Abstract

Our recent stress-controlled measurements show that a sufficient yet moderate level of chain deformation due to shear can produce spatial topological rearrangement to free chains from mutual dynamic constraint [1]. The chain disentanglement seems to occur catastrophically, resulting in an inhomogeneously sheared sample during rate-controlled shear [2]. Thus, chain disentanglement is also expected to take place during large amplitude oscillatory shear (LAOS) at frequencies higher than the overall chain relaxation rate. We applied our particle-tracking velocimetric technique to probe the state of chain entanglement during LAOS. We found that the chain orientation produced by LAOS led to a new environment in which the initially well-entangled chains managed to disentangle inhomogeneously in space. A layer free of chain entanglement developed to take the load of the imposed strain. As a result of this nonlinearity, the rest of the sample avoided significant deformation and its chain entanglement remained intact. [1] Tapadia, P.; Wang, S. Q. Phys Rev. Lett, 91, 198301 (2003); Tapadia, P.; Wang, S. Q. Macromolecules 37, 9083 (2004). [2] Tapadia, P.; Wang, S. Q. Phys. Rev. Lett. , in press (2005).

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