Polymer Science Faculty Research
Title
An all-atom simulation study of the ordering of liquid squalane near a solid surface
Document Type
Article
Publication Date
Summer 2008
Abstract
An all-atom molecular dynamics study using the OPLS force field has been carried out to obtain new insights in to the orientation and ordering of liquid squalane near a solid surface. As observed in previous experiments, the squalane molecules closest to a SiO2 substrate are found to be tightly bound with their molecular axis preferentially parallel to the interface. Unlike linear alkanes, the squalane molecules are also found to lie preferentially parallel to the liquid/vapor interface. The simulation results predict that the molecular plane orientation of the squalane molecules changes from mainly parallel to perpendicular to the substrate in going further away from the substrate.
Volume
457
First Page
357
Last Page
361
Recommended Citation
Tsige, Mesfin, "An all-atom simulation study of the ordering of liquid squalane near a solid surface" (2008). Polymer Science Faculty Research. 349.
https://ideaexchange.uakron.edu/polymerscience_ideas/349