Chemical and Biomolecular Engineering Faculty Research

Title

High-resolution in Situ and Ex Situ Tem Studies on Graphene Formation and Growth on Pt Nanoparticles

Document Type

Article

Publication Date

Fall 2011

Abstract

The formation of graphene layers on MgO-supported Pt nanoparticles was studied by both in situ and ex situ high-resolution transmission electron microscopy (HRTEM). The HRTEM images indicate that graphene sheets grow from steps in the surface of Pt nanoparticles. The subsequent morphology of the graphene sheets is a strong function of Pt particle size. For particles less than ∼6 nm in diameter, the graphene sheets form nanotubes or move from the surface of Pt particles and accumulate on the MgO support. Complete particle envelopment by multiple graphene layers was only observed for particle greater than ∼6 nm in diameter. The observed dependence of graphene morphology on Pt nanoparticle size and shape is associated with the strain energy generated between graphene layers during their growth and the overall free energy of the graphene-Pt system.

Volume

286

First Page

22

Last Page

29