College

College of Engineering and Polymer Science

Date of Last Revision

2025-04-26 12:10:39

Major

Chemical Engineering

Honors Course

CHEE 497

Number of Credits

3

Degree Name

Bachelor of Science

Date of Expected Graduation

Spring 2025

Abstract

The proposed research develops and studies catalytic chemical processes that enables using polystyrene (PS) plastic waste as solid “organic hydrogen carriers” (OHC). Demands for OHCs are driven by desire to alleviate climate change, by replacing carbon-based energy sources with hydrogen. However, hydrogen is highly flammable and difficult to store and transport so OHCs are needed to facilitate its transportation. Common OHCs are liquid petroleum chemicals with unsaturated chemical structures. They can be hydrogenated to store hydrogen and dehydronated to release hydrogen at desired application sites. The proposed research aims to investigate the following cycle: hydrogen storage by hydrogenation of PS to poly(vinyl-cyclohexane) (PVCH) over cheap, sustainable nickel-based (Ni) catalysts, transportation as a solid, then on-site dehydrogenation back to PS. The motivations for this work not only come from a desire to use OHCs to reduce the impact of plastic waste on climate change, but also for the desire and need to reduce plastic waste. If this research is successful, polystyrene waste from plastics will be repurposed. Repurposing this waste reduces landfill waste, pollution, and the need to purchase new materials, which consequently saves costs. As polystyrene is a solid, it also allows for cheaper and safer transportation than the liquid OHC alternatives.

Research Sponsor

Linxiao Chen

First Reader

Roya Gitiafroz

Second Reader

Bi-min Newby

Honors Faculty Advisor

Donald Visco

Proprietary and/or Confidential Information

No

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