Polymer Science Faculty Research
Title
Poly(beta-alanoid-block-beta-alanine)s: Synthesis via cobalt-catalyzed carbonylative polymerization and self-assembly
Document Type
Article
Publication Date
5-19-2010
Abstract
The titled diblock copolymers are synthesized via cobalt-catalyzed living carbonylative polymerization of N-alkylaziridines under moderate pressures followed by a deprotection step. The poly(beta-alanine) block is solubilized by the poly(beta-alanoid) block in chloroform and remains fully hydrogen-bonded in the form of a sheet-like assembly.
Publication Title
Chemical Communications
Volume
46
Issue
24
First Page
4273
Last Page
4275
Recommended Citation
Lin, Shaohui; Yu, Xinfei; Tu, Yingfeng; Xu, Hongyu; Cheng, Stephen Z. D.; and Jia, Li, "Poly(beta-alanoid-block-beta-alanine)s: Synthesis via cobalt-catalyzed carbonylative polymerization and self-assembly" (2010). Polymer Science Faculty Research. 284.
https://ideaexchange.uakron.edu/polymerscience_ideas/284