Chemical and Biomolecular Engineering Faculty Research

Title

A Method for Measuring the Corrosion Rate of Materials in Spallation Neutron Source Target/blanket Cooling Loops

Document Type

Article

Publication Date

Fall 1999

Abstract

This paper summarizes the ongoing evaluation of the susceptibility of materials in accelerator target/blanket cooling loops to corrosion. To simulate the exposure environment in a target/blanket cooling loop, samples were irradiated by an 800MeV proton beam at the A6 Target Station of the Los Alamos Neutron Science Center (LANSCE). To accomplish this, a cooling water loop capable of exposing corrosion samples to an 800MeV proton beam at currents upwards of 1 mA was constructed. This loop allowed control and evaluation hydrogen water chemistry, water conductivity, and solution pH. Specially designed ceramic sealed samples were used to measure the real-time corrosion rates of materials placed directly in the proton beam using electrochemical impedance spectroscopy (EIS). EIS was also used to measure real-time corrosion rates of samples that were out of the proton beam and “downstream” from the in-beam samples. These out-of-beam probes primarily examined the effects of long lived water radiolysis products from proton irradiation on corrosion rates. An overview of the LANSCE corrosion loop, the corrosion probes, and data from an in-beam alloy 718 probe are presented. Published by Elsevier Science Inc.

Volume

43

Issue

3

First Page

135

Last Page

145